Friday, March 20, 2020

Litotes

Litotes Litotes Litotes By Maeve Maddox A rhetorical term for understatement is litotes: litotes [LY-tuh-teez] (noun): understatement in which an affirmative is expressed by the negative of the contrary (as in â€Å"Hes not a bad ballplayer†)- Merriam-Webster. Litotes can be used to express a variety of meanings. When the translators of the KJV have Paul of Tarsus identify himself to the Roman officer as â€Å"a citizen of no mean city† (Acts 21:39), it is not to suggest that Paul was being modest. The words are â€Å"no mean city,† but the meaning is â€Å"a very important city.† Here are other examples of the use of litotes to emphasize the importance of something by using a negative to express the contrary: The history of American freedom is,  in no small measure, the history of procedure.  (i.e., â€Å"to a great extent†) The disparity in government funding is  not easy  to remedy. (i.e, â€Å"extremely difficult†) Litotes is also used to convey modesty, sarcasm, contempt, admiration, and veiled disapproval, as in the following examples: You’ve managed to wreck the car and destroy the front porch all in one go. Good job! He’s no Einstein. Oprah gave every guest a car? Not too shabby. This day-old lobster bisque is not entirely inedible. Understatement has been a popular form of expression in English since the earliest times. For example, the Old English epic Beowulf begins with a gory description of Grendel’s slaughter of thirty of Hrothgar’s thanes. Grendel seizes the thanes and carries some of the bloody bodies back to his lair, â€Å"exulting.† Later, Grendel returns to wreak more slaughter. Says the poet, â€Å"[The monster] did not mourn for it.† Want to improve your English in five minutes a day? Get a subscription and start receiving our writing tips and exercises daily! Keep learning! Browse the Vocabulary category, check our popular posts, or choose a related post below:70 "Home" Idioms and ExpressionsWhen to Form a Plural with an ApostropheThe Difference Between "Un-" and "Dis-"

Wednesday, March 4, 2020

Nitrogen Triiodide Chemistry Demonstration

Nitrogen Triiodide Chemistry Demonstration In this spectacular chemistry demonstration, crystals of iodine are reacted with concentrated ammonia to precipitate nitrogen triiodide (NI3). The NI3 is then filtered out. When dry, the compound is so unstable that the slightest contact causes it to decompose into nitrogen gas and iodine vapor, producing a very loud snap and a cloud of purple iodine vapor. Difficulty: Easy Time Required: Minutes Materials Only a few materials are required for this project. Solid iodine and a concentrated ammonia solution are the two key ingredients. The other materials are used to set up and execute the demonstration. up to 1 g iodine (do not use more)concentrated aqueous ammonia (0.880 S.G.)filter paper or paper towelring stand (optional)feather attached to a long stick How To Perform the Nitrogen Triiodide Demo The first step is to prepare the NI3. One method is to simply pour up to a gram of iodine crystals into a a small volume of concentrated aqueous ammonia, allow the contents to sit for 5 minutes, then pour the liquid over a filter paper to collect the NI3, which will be a dark brown/black solid. However, if you grind the pre-weighed iodine with a mortar/pestle beforehand a larger surface area will be available for the iodine to react with the ammonia, giving a significantly larger yield.The reaction for producing the nitrogen triiodide from iodine and ammonia is:3I2 NH3 → NI3 3HIYou want to avoid handling the NI3 at all, so my recommendation would be to set up the demonstration in advance of pouring off the ammonia. Traditionally, the demonstration uses a ring stand on which a wet filter paper with NI3 is placed with a second filter paper of damp NI3 sitting above the first. The force of the decomposition reaction on one paper will cause decomposition to occur on the other pa per as well. For optimal safety, set up the ring stand with filter paper and pour the reacted solution over the paper where the demonstration is to occur. A fume hood is the preferred location. The demonstration location should be free of traffic and vibrations. The decomposition is touch-sensitive and will be activated by the slightest vibration.To activate the decomposition, tickle the dry NI3 solid with a feather attached to a long stick. A meter stick is a good choice (dont use anything shorter). The decomposition occurs according to this reaction:2NI3 (s) → N2 (g) 3I2 (g)In its simplest form, the demonstration is performed by pouring the damp solid onto a paper towel in a fume hood, letting it dry, and activating it with a meter stick. Tips and Safety Caution: This demonstration should only be performed by an instructor, using proper safety precautions. Wet NI3 is more stable than the dry compound, but still should be handled with care. Iodine will stain clothing and surfaces purple or orange. The stain can be removed using a sodium thiosulfate solution. Eye and ear protection are recommended. Iodine is a respiratory and eye irritant; the decomposition reaction is loud.NI3 in the ammonia is very stable and can be transported, if the demonstration is to be performed at a remote location.How it works: NI3 is highly unstable because of the size difference between the nitrogen and iodine atoms. There is not enough room around the central nitrogen to keep the iodine atoms stable. The bonds between the nuclei are under stress and therefore weakened. The outside electrons of the iodine atoms are forced into close proximity, which increases the instability of the molecule.The amount of energy released upon detonating NI3 exceeds that requ ired to form the compound, which is the definition of a high yield explosive.